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Beilstein J. Org. Chem. 2020, 16, 1579–1587, doi:10.3762/bjoc.16.130
Graphical Abstract
Scheme 1: Literature-reported cycloaddition reactions of MBH acetates involving azides and alkynes [24-28].
Scheme 2: Synthetic methodologies for triazolations of MBH adducts. a) Literature-reported indirect triazolat...
Scheme 3: Scope of the one-pot cascade reaction of the unprotected Morita–Baylis–Hillman adducts 3a–q.
Figure 1: Proposed mechanism for the synthesis of 1,4-disubstituted triazoles.
Scheme 4: Comparative analysis of the sequential one-pot reaction.
Figure 2: Proposed mechanism for the synthesis of 3-(bromomethyl)coumarins.